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Nembutal (pentobarbital sodium) is used short-term to treat insomnia. It is also used as an emergency treatment for seizures, and to cause patients to fall asleep for surgery. Nembutal is in the barbiturate drug class, and acts as a depressant, or sedative. This medication is available in generic form.Nembutal (pentobarbital sodium) is used short-term to treat insomnia. It is also used as an emergency treatment for seizures, and to cause patients to fall asleep for surgery. Nembutal is in the barbiturate drug class, and acts as a depressant, or sedative. This medication is available in generic form.Nembutal (pentobarbital sodium) is used short-term to treat insomnia. It is also used as an emergency treatment for seizures, and to cause patients to fall asleep for surgery. Nembutal is in the barbiturate drug class, and acts as a depressant, or sedative. This medication is available in generic form.